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IsoFLUX – Integrating Contaminant Mass Flux and Isotope Analysis

IsoFLUX: Measure Mass Flux and Biodegradation in a Single Deployment

Traditional monitoring programs often rely on concentration measurements from monitoring wells, which can miss important information about contaminant migration and degradation. IsoFLUX combines passive mass flux measurements with compound-specific isotope analysis (CSIA) to provide a more representative assessment of contaminant loading, transport, and in situ biodegradation.

By integrating contaminant mass flux data with isotopic enrichment trends, IsoFLUX helps practitioners determine whether natural attenuation or remedial activities are effectively reducing contaminant mass discharge.

WHY CONCENTRATION DATA ALONE CAN BE MISLEADING

Concentration Measurements Represent a Moment in Time

Concentration measurements obtained from conventional monitoring wells represent conditions at a single point in time and space. Concentrations can fluctuate due to:

  • Groundwater level changes
  • Seasonal variability
  • Sampling methodology
  • Well construction effects
  • Heterogeneous contaminant distribution

As a result, concentration trends alone may not accurately represent contaminant loading or treatment performance.

LIMITATIONS OF CONCENTRATION-BASED MONITORING

  • Concentration does not equal mass discharge.
  • Declining concentrations do not necessarily indicate plume stability.
  • Concentration trends rarely identify degradation mechanisms.

TIME-INTEGRATED FLUX MEASUREMENTS

Passive flux samplers provide a time-integrated measurement of groundwater flow and contaminant transport, reducing uncertainty associated with conventional grab sampling.

Why It Matters

Decisions regarding remedy performance, monitored natural attenuation, and site closure should not rely solely on concentration trends. Time-integrated measurements of contaminant mass flux and isotopic composition provide a more representative assessment of plume behavior, risk reduction, and treatment effectiveness.

WHAT IS ISOFLUX?

IsoFLUX combines passive groundwater and contaminant flux measurements obtained using iFLUX technology with compound-specific isotope analysis (CSIA) to simultaneously evaluate groundwater flow, contaminant mass flux, isotopic composition, and changes in degradation pathways.

KEY BENEFITS

  • Time-integrated sampling
  • Multiple lines of evidence
  • Quantifies contaminant mass discharge
  • Evaluates biodegradation processes
  • Optimizes remediation strategies
  • Supports regulatory closure

IsoFLUX → Mass Flux + CSIA = Stronger Evidence

Together, mass flux and CSIA make IsoFLUX a powerful one-two punch for remediation performance monitoring:

  • Mass flux quantifies how much contaminant mass is still moving.
  • CSIA shows that contaminants are being destroyed, not just diluted.

Smarter Decisions, Better Outcomes

By integrating molecular-scale evidence (CSIA) with plume-scale transport data (mass flux), IsoFLUX provides project teams with a dataset that goes beyond concentrations—capturing the real flow of contaminants and their fate in the environment.

IsoFLUX allows site managers to:

  • Differentiate dilution from destruction
  • Quantify reductions in mass discharge
  • Build stronger cases for monitored natural attenuation (MNA) or remedy effectiveness
  • Provide regulators with a clear, defensible line of evidence

Bottom line: CSIA tells you what’s happening at the molecular level. Mass flux shows you how much contaminant is moving. Together, IsoFLUX provides the clarity needed to demonstrate real progress toward remediation goals.

ISOFLUX Mass Flux CSIA

 IsoFLUX Applications

IsoFlux can be applied throughout the project lifecycle - from site characterization to remedy optimization, performance monitoring, and site closure support.

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Monitored Natural Attenuation (MNA)

 Evaluate whether natural attenuation processes are effectively reducing contaminant mass discharge and supporting plume stability.

 

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Enhanced Bioremediation

 Track changes in contaminant mass flux and isotopic composition to verify biodegradation and optimize amendment applications.

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Performance Monitoring

Measure changes in contaminant loading over time to assess remedial performance and support adaptive site management,

 

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Remedy Optimization

 Identify areas of persistent contaminant loading and optimize treatment strategies based on multiple lines of evidence. 

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Site Closure

 Provide robust lines of evidence demonstrating remedy effectiveness and long-term risk reduction to support regulatory closure.

 

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Source Zone Management

 Delineate persistent source areas, quantify contaminant loading, and evaluate source depletion over time to guide remedial decision-making.

Target Contaminants & Isotope Systems

Tersus supports CSIA investigations for a broad range of contaminants using multiple stable isotope systems tailored to site-specific objectives.

Contaminant Group   Common Isotopes
Chlorinated Solvents   δ¹³C, δ²H, δ³⁷Cl
Petroleum Hydrocarbons   δ¹³C, δ²H
MTBE & Fuel Oxygenates   δ¹³C, δ²H
Explosives   δ¹⁵N, δ¹³C
Nitrate   δ¹⁵N, δ¹⁸O
Other Emerging Contaminants  

Additional isotope systems are available based on project objectives.
Contact Tersus to discuss site-specific applications.

Interested in Applying IsoFLUX at Your Site

Whether you are evaluating monitored natural attenuation, optimizing remediation performance, or supporting site closure, Tersus can help design and implement an IsoFLUX investigation tailored to your site objectives.

Request A Site Evaluation